The controllable regulation of dimensionality and interpenetration in covalent organic frameworks (COFs) is crucial for optimizing photocatalytic performance, yet the translation of 3D COFs from structural construction to functional customization remains challenging. Here, we successfully designed a series of mortise-a...
Polystyrene (PS) waste is exceptionally difficult to chemically degrade under environmental conditions, and the high-value utilization of low-value C1 products generated during the process has never been achieved. Herein, we constructed a metalloporphyrin-anthracene sp2 covalent-organic framework (COF) electrocatalyst,...
Polymers constitute indispensable functional components across energy, environmental, and biomedical applications, yet precise control over their primary and higher-order structures remains a core challenge. Covalent organic frameworks (COFs), a class of crystalline porous materials featuring designable topologies, tun...
Fullerenes are a unique class of stable molecular clusters whose structural evolution is constrained by the geometry and topology of pentagon-hexagon arrangements of sp2-hybridized carbons with (p-p)π conjugation. However, extending this geometry- and topology-driven structural evolution to other inorganic systems rema...
Di Zhang, Xiao-Kun Zhao, Fengxue Duan et al.· Proceedings of the National...· 0 citations
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