Poly(ionic liquid)-Grafted MOF Gels: A Co-catalyst-free Platform for High-Efficiency CO2 Cycloaddition.
Poly(ionic liquid)-grafted UiO-66-NH2 gels are developed as a high-performance and co-catalyst-free platform for efficient CO2 capture and chemical fixation under mild conditions. To address the mass transfer limitations and high energy barriers typical of purely microporous powder materials, a series of hierarchically...