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Zakaria Halime

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Open access Sep 2026

Direct Observation of a Hydrogen-Bonding Assisted Quasi-Reversible Superoxo/Peroxo Interconversion in a Heme Model.

The activation and reduction of molecular oxygen at transition metal centers are central to both enzymatic catalysis and energy conversion. Here, we report the first direct observation of a hydrogen-bonding-assisted, quasi-reversible superoxo (FeIII─O2˙-)/peroxo (FeIII─O2 2-) redox couple in a heme model complex using...

Adelais Trapali, Régis Guillot, Christian Herrero et al. · 0 citations

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