Solvent–Solvent Anchoring Decouples Non‐Flammability and Interfacial Stability in Sodium Metal Batteries
Non‐flammable phosphate electrolytes are attractive for safe sodium metal batteries, but their strong coordination with Na + and continuous interfacial decomposition impose a fundamental safety‐reactivity trade‐off. Here, we develop a solvent‐centric molecular anchoring strategy to regulate electrolyte chemistry...