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Integrated biorefinery for cellulosic ethanol and spherical nanolignin production from coconut waste

Aug 2026 · Biofuels, Bioproducts and Biorefining · 0 citations · 49 references

Abstract

Green coconut waste was subjected to different fractionation methods to obtain integrated lignin nanoparticles and cellulosic ethanol. Pretreatment with gradual addition of dilute sulfuric acid provided a higher structural hemicellulose precursor yield (68.2%). Alkaline treatment resulted in the highest extraction and recovery of lignin from coconut waste, at 79.5% and 25.3%, respectively. Separate hydrolysis and fermentation indicated that slow acid addition followed by alkaline treatment rendered the coconut biomass more susceptible to enzymatic digestion, achieving sugar yields above 60% and an ethanol yield of 0.48 (w/w). Alkaline lignin from coconut fibers was successfully converted into nanometric structures of spherical conformation ( Ø  = 80–600 nm) with a high degree of uniformity, homogeneous dispersion, and colloidal stability, with weight yields of 30% to 50%. Thus, utilizing coconut waste to obtain cellulosic ethanol and lignin nanoparticles is feasible and results in value‐added products and an environmentally sustainable alternative to waste disposal.

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