Similar papers
Sep 2026
Elucidation of Macrocycle-Derived Covalent Organic Framework Film Formation through Interfacial Linker Exchange.
Over the past decade, postsynthetic linker exchange (PLE) has emerged as a promising strategy for fabricating high-quality covalent organic frameworks (COFs), leveraging the principles of dynamic covalent chemistry (DCC). However, the synthetic challenges posed by the complex parent entities used in PLE, such as COFs a...
G. Shreeraj, Vishal Ghule, Madhvi Tiwari et al.
· ACS Applied Materials and In... · 0 citations
Open access
Sep 2026
Single cobalt atoms and two oxidation states: on-surface synthesis of a 2D metal–organic framework via transmetallation
Characterizing the chemical and physical properties of metal–organic frameworks (MOFs) is crucial for harnessing their unique functionalities in the design of next-generation catalysts and spintronic materials. Here, we report the formation of a homometallic MOF via co-deposition of Mn-tetrapyridylporphyrin (MnTPyP) mo...
V. Mischke, Olga Resel, Dominik Brandstetter et al.
· Nanoscale · 0 citations
Sep 2026
Interpenetration Transformation of Diacetylene Metal-Organic Frameworks for Topochemical Polymerization.
Achieving precise control over topochemical polymerization in diacetylene metal-organic frameworks (MOFs) remains a huge challenge due to the stringent requirements for molecular alignment and ordered stacking. Herein, we report two interpenetrated MOFs (twofold interpenetrated CAS-20 and threefold interpenetrated CAS-...
Zhi-Bin Jin, Qi-Qi Zhang, Li-Mei Chang et al.
· Angewandte Chemie · 0 citations
Open access
Aug 2026
Flux-mediated ligand exchange restructures metal-organic framework glasses.
Melt-quenched glasses derived from metal-organic frameworks (MOFs) combine the processability of glasses with the modularity and microporosity of MOFs, yet remain structurally and functionally less diverse than crystalline analogues. Here we show that the chelating ligand 1,10-phenanthroline acts as an organic flux tha...
Jan-Benedikt Weiß, Lorena Fritsch, Michele Tricarico et al.
· Nature Materials · 2 citations
Sep 2026
Deciphering Dynamic Self-Healing for Crystallinity Control in β-Ketoenamine-Linked Covalent Organic Frameworks.
Covalent organic frameworks derived from triformylphloroglucinol (Tp-COFs) represent a prominent branch of COFs due to their high potential in separation, energy storage, and optoelectronics. However, the development of Tp-COFs is often hindered by limited crystallinity, resulting from the low reversibility of β-ketoen...
Fan Qiu, Lei Gao, Yu-Bin Fu et al.
· Angewandte Chemie · 0 citations
Open access
Sep 2026
Stimuli-induced reversible transformation between isomers of copper(I) clusters sharing an identical core.
The construction of reversible structural isomerization in atomically precise metal clusters remains a daunting challenge. Herein, we report the application of a bifunctionalized phosphine-alkyne ligand, (2-ethynylphenyl)diphenylphosphine (HL), to synthesize an octanuclear copper(I) cluster Cu8-1 [(Cu8(L)6(PF6)2], whic...
Yao Wang, Fang-Xue Xiao, Zi-Yong Chen et al.
· Proceedings of the National... · 0 citations