Work extraction from nonequilibrium systems is a major challenge across biological, chemical, physical, and engineering systems. Idealized protocols generally require a quasistatic relaxation stage in which the Hamiltonian is gradually adjusted through a continuum of intermediaries. Here, we consider protocols restricted to a finite number $N$ of intermediary Hamiltonians, consisting of a sequence of quench-relax steps. We determine the sequence of quenches that minimizes the dissipated work, which can be expressed in terms of a recurrence involving the Lambert function. The optimal sequence converges to the Fisher-Rao geodesic, saturating known leading-order dissipation bounds at large $N$. We obtain lower bounds on work extraction from a nonequilibrium distribution as a function of its Fisher-Rao distance to equilibrium. We extend and apply the framework in two simple models: (i) an optical trap experiment, showing that the optimal intermediary distribution can be bimodal even for unimodal initial and final distributions, and (ii) an enzyme-catalyzed reaction, showing that that accounting for relaxation time in addition to dissipation can favor barrier-lowering.
Metastability separates apparent equilibration from true convergence: a dynamical system can remain near an intermediate state long before reaching its stationary state. In quantum dynamics used for optimization, such a plateau can delay progress toward a target concentrated near the global minimizers of a nonconvex po...
Inspired by the chemical reaction network considered as the smallest system featuring a Hopf bifurcation and its reversible extension, we introduce an even more minimal reaction network that is thermodynamically consistent and exhibits autonomous oscillations under nonequilibrium driving. The model combines three featu...
Benedikt Remlein, L. Monari, Beatrice Bartolomei et al.· 0 citations
Markovian open-system dynamics have widespread applications throughout quantum information science, including algorithmic state preparation. Their convergence is commonly quantified using the worst case global trace distance between the evolving and stationary states. However, this criterion can be unnecessarily string...
Štěpán Šmíd, Richard Meister, Mario Berta et al.· 1 citation
We investigate the relaxation of an approximately conserved charge in interacting quantum systems close to local equilibrium. To this end, we provide a pedagogical review of Zubarev's non-equilibrium statistical operator approach in the minimal setting of a single non-conserved charge and apply it to the problem at han...
Matthias Carosi, B. Garbrecht, Silvia Pla et al.· 0 citations
The Jarzynski relation enables the estimation of equilibrium free energy differences from non-equilibrium, finite-time switching simulations. These estimates usually converge poorly because rare trajectories dominate the exponential work average. Here, we numerically determined and explored the sequence of intermediate...
We present a theory for the optimal control of stochastic systems in structured environments, represented by penalty terms in the cost functional. We show that such control problems generically feature sharp finite-time transitions associated with a qualitative change in the control strategy at a critical time. Startin...
Jan Meibohm, Samuel Monter, Clemens Bechinger et al.· 1 citation
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