Emergent Second Law for Time-Dependent Nonequilibrium States

Abstract

For nonautonomous open systems described by macroscopic stochastic thermodynamics, we derive an emergent second law that constrains time-dependent macroscopic fluctuations by the entropy production along the most probable evolution under the time-reversed driving protocol. We show that this bound can be understood as a macroscopic consequence of the fluctuation theorem: the time reverse of this evolution provides a possible fluctuation path under the forward dynamics. In the linear-response and slow-driving regime, the bound becomes an equality to first order and generalizes the McLennan-Zubarev formula to the time-dependent probability density of nonautonomous systems with weak nonconservative affinities. We illustrate our results in a bistable system under sudden quenches and periodic driving.