Odd stochastic density functional theory

Abstract

Stochastic density functional theory (SDFT) provides a powerful framework for studying the dynamics of many-body systems both in and out of equilibrium. In its standard form, it can be viewed as a density-based formulation of coupled Langevin equations with white noise. Here, we extend SDFT to a class of systems, ranging from magnetized electrolytes to chiral active matter, that possess a chiral overdamped limit in which a relaxation timescale and an oscillation period are simultaneously taken to zero. We derive this formulation, which we dub ``odd SDFT", by taking the overdamped limit of a fluctuating hydrodynamic description of underdamped particles subject to a Lorentz force. We establish the validity and utility of the resulting framework by calculating the collective mobility tensor of interacting particles using both direct linear response and a Green-Kubo relation. We then apply the theory to the Hall conductivity of electrolytes in magnetic fields. Going beyond mean-field theory and using two distinct Green-Kubo relations, we derive the full conductivity tensor, extending the relaxation part of the Debye-H\"uckel-Onsager theory to the case of finite magnetic fields.