THE EL-RAKHAWI 24/7 QUANTUM-ENHANCED SOLAR ENERGY ARCHITECTURE (QESEA) An Integrated Framework for Singlet Fission-Augmented Perovskite Tandems, AI-Discovered 2D/3D Stabilization, and Thermoradiative Night-Time Generation
Abstract
THE EL-RAKHAWI 24/7 QUANTUM-ENHANCED SOLAR ENERGY ARCHITECTURE (QESEA) by Dr. M.K.A. El-Rakhawi (DOI: 10.5281/zenodo.23548358) presents a revolutionary framework shattering the Shockley-Queisser limit and solar intermittency through four synergistic pillars. **Core Innovations:**1. **Singlet Fission Augmentation**: Organic chromophores split high-energy photons into two triplet excitons, with a specifically designed spin-orbit coupling interlayer (heavy-metal-atom-doped molecular linkers) mediating efficient triplet energy transfer to overcome spin-forbidden transition barriers. 2. **AI-Discovered 2D/3D Perovskite Heterostructure**: Graph neural networks identify fluorinated phenethylammonium (F-PEA) derivatives, applied via vapor-assisted deposition protocol to form an impermeable 2D capping layer ensuring >25-year operational stability under ISOS-L-3 protocols. 3. **Thermoradiative Diode Integration**: Narrow-bandgap semiconductors (compositionally graded HgCdTe) emit mid-infrared radiation to 3K space through the 8-13 µm atmospheric window, generating continuous, low-density (microwatt to milliwatt per m²) nocturnal baseline power. 4. **AI-Driven Solid-State Grid Orchestration**: Edge-computing controllers physically actuate battery charge controllers and grid inverters, satisfying the machine-or-transformation test by tangibly altering the physical state of the energy grid. IP protection excludes natural phenomena per Alice/Myriad precedents, safeguarding only concrete implementations (spin-orbit interlayers, F-PEA deposition protocols, thermoradiative diode integration, physical actuation mechanisms), ensuring robust patent eligibility for this 24/7 renewable energy breakthrough.
