Quantum mechanics is widely recognised as being incomplete. It is not consistent with the second law of thermodynamics and does not provide a scientifically credible physical account of the measurement process, the means by which coherence is broken and classically observable states are recorded. This has led to many ad hoc assumptions being used to account for various properties of quantum systems, among which is the coherence time of quantum devices that determines their ability to perform computations. Here, we show that all these properties can be accommodated naturally and consistently in the context of quantum systems which exhibit continuous spectra, as arises in the thermodynamic limit of large systems. In particular, for isolated systems we show that the time-reversal symmetry associated with unitary time evolution of the quantum state gives rise to time-symmetry breaking and a semi-group evolution which attains thermodynamic equilibrium at long times. Moreover, the emergence of this non-unitary time-asymmetry leads to microcanonical equilibrium states in which all quantum coherence is lost and is accompanied by the transformation of pure states into mixtures, leading in turn to an increase in entropy. Inclusion of a macroscopic measurement apparatus shows how the outcome of a measurement corresponds to the von Neumann projection postulate, arising with probabilities in conformance with the Born rule. The mathematical structure of the theory which applies to quantum systems with continuous spectra is closely analogous to the classical ergodic theory of dynamical systems and the conditions under which they attain equilibrium states.
The Born rule for computing probabilities of the outcomes of measurements is an indispensable ingredient of quantum mechanics. The standard textbook description of this rule gives the impression that it implies the unitarity of time evolution. This view relies on the argument that unless the dynamics is unitary, the probabilities of finding all possible outcomes of a measurement do not add up to 1, i.e., the total probability is not conserved. We show that this argument is flawed, and that the general expression for the Born rule ensures the conservation of total probabilities even when the dynamics of a quantum system is not unitary. This applies to the dynamics of ensembles of quantum systems in both pure and mixed states. We discuss the status of the local conservation of probabilities and the arguments against the plausibility of non-unitary time evolutions that are based on the identification of the Hamiltonian operator with the energy observable.
The physical content of a theory is not intrinsically tied to any single mathematical formalism. Both classical and quantum mechanics admit equivalent representations, notably in phase space and in Hilbert space, related by the Wigner-Weyl correspondence. While this correspondence has long been studied in mathematical physics, its foundational and operational implications are often left implicit. Here we give a systematic account of what changes, and what does not, when classical and quantum theories are expressed in each other's native language. This representational viewpoint separates artifacts (such as the appearance of non-positivity or negativity under certain maps) from robust structural distinctions that persist across representations, in particular noncommutativity and its $\hbar$-dependent $\star$-deformation of the classical algebra. We develop the comparison at the level of states, kinematics, and dynamics, and extend it to measurement by formulating both outcome statistics and state-update rules within the same framework.
S. Schlegel, Borivoje Daki'c, Flavio Del Santo· 0 citations
We challenge the common belief that if there is no absolute time parameter in physics, a quantum system described without reference to an external clock can be assumed to be in a stationary state of its Hamiltonian. We present a time-reparameterisation invariant quantum evolution law, which for a given initial condition predicts the same trajectory in state space as the Schr\"odinger equation, except that for nontrivial trajectories it does not predict the speed at which the trajectory is traversed. The solutions of this evolution law are all time-reparameterised solutions of the Schr\"odinger equation. We show how the predictions of the Schr\"odinger equation are recovered relative to an internal clock in this framework. In contrast to the Page-Wootters formalism or Dirac's quantisation of the Hamiltonian constraint, here the global sate is not stationary. We discuss the assumptions leading to the common conclusion that the state can be taken stationary and suggest that they need to be revisited.
Temperature is one of the central concepts of thermodynamics, yet its meaning far from equilibrium remains unclear. The problem is especially challenging in isolated quantum many-body systems, whose states evolve unitarily, may remain far from equilibrium, and retain energy coherence, a genuinely quantum feature with no direct classical counterpart. Specifically, energy fluctuations in a nonstationary quantum state have two distinct origins. Part of them comes from uncertainty in the energy populations and has the usual thermodynamic meaning. The rest comes from quantum coherence between energy sectors and is responsible for the state's time dependence. We propose that, even away from equilibrium, temperature identifies the state within the family of regular states sharing the same energy-coherence structure. This provides a natural definition of temperature for a broad class of nonequilibrium quantum states. The resulting inverse temperature is not, in general, obtained by differentiating entropy with respect to energy. The usual maximum-entropy principle is instead replaced by a principle of minimum discrimination information, which selects the least distinguishable state compatible with the prescribed energy and coherence structure. We also extend the construction to subsystems and show that, although their inverse temperature is not determined by the reduced state alone, its instantaneous rate of change is a local quantity, determined by the thermodynamic structure induced on the subsystem at that time.
Quantum theory challenges the view that individual measurement outcomes are predefined and independent of the measurement context. Yet the quantum state itself -- the catalogue of probabilities for all possible measurements -- is usually assumed to be well defined. We argue that this assumption tacitly relies on measurements being performed relative to ideal, infinitely-resourceful reference frames. We show that, when measurements are made relative to non-ideal quantum reference frames, the probabilities themselves become indefinite: even in the limit of arbitrarily large number of runs, the relative frequencies may remain uncertain. The uncertainty is irreducible in a quantum-mechanical sense, as we show by proving a Bell-type theorem for relative frequencies. We further propose a quantum-optical implementation of these relational measurements based on pulsed homodyne detection. Our findings motivate an extension of the notion of the quantum state to regimes constrained by finite resources. We expect them to be especially relevant at the interface between quantum theory and general relativity, where the resources and information available in a bounded region of spacetime are fundamentally limited.
Esteban Castro-Ruiz, Nathan Cohen, L. Barbado et al.· 0 citations
We build a framework for the thermodynamics of macroscopic quantum systems. In contrast with approaches requiring access to the full density matrix, our framework relies on a coarse-grained description, based on measurement statistics of a few observables. When these observables commute, the outcomes define classical macrostates whose entropy is quantified by observational entropy, accounting for uncertainty about both the macrostate and the microstate within it. We extend this notion to non-commuting observables forming a subalgebra of the operator space, and use Jaynes'principle to define an algebra-dependent entropy interpolating between von Neumann and observational entropies. Given initial and final measurement sets, connected by internal and/or environment-induced dynamics, we derive a second law for the coarse-grained dynamics. Unlike formulations based on von Neumann entropy, our inequality captures irreversibility from both non-unitary environment-induced dynamics and internal equilibration. It takes the usual form of a positive entropy production when the system is initially at internal equilibrium, while correction terms capture nonequilibrium resources ignored by the coarse-graining. We also derive fluctuation theorems for coarse-grained thermodynamic quantities. Along a quasi-static path of measurement schemes, we identify quantum macroscopic notions of work and heat fulfilling the first and second laws, including an additional work contribution from manipulating the algebra to which the system is confined, through external constraints or quantum measurement backaction. Finally, we apply our framework to examples illustrating the impact of varying the coarse-graining scheme. Our approach unifies macroscopic and stochastic thermodynamics in a genuinely quantum framework, laying the basis for a versatile, experimentally friendly toolbox to analyze complex quantum dynamics.