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Open access Aug 2026

Supramolecular morphological transition driven by nonequilibrium break-and-build self-organisation

Controlling the nonequilibrium dynamics in synthetic systems is an important challenge in supramolecular chemistry. Biological morphogenesis exploits nonequilibrium reaction–diffusion processes to organise differentiated cell networks and functions in space. In contrast, artificial assemblies are mostly formed under th...

Ryou Kubota, Yuriki Ikuta, Shogo Torigoe et al. · 0 citations
Sep 2026

Construction of Orientationally Ordered Organometallic Chains by Directional Noncovalent Interactions

Achieving orientational control during on-surface synthesis remains a major challenge because conventional approaches mainly rely on steric effects or substrate templating, which often lack chemical versatility. Here, we demonstrate that directional noncovalent interactions can regulate hierarchical reaction pathways...

Jie Li, Zhen Xu, Hong-Xiang Xu et al. · 0 citations
Review Sep 2026

Structural programming of inorganic materials using DNA frameworks.

Supramolecular assembly through non-covalent interactions is an attractive strategy for building ordered functional systems. DNA exhibits precise programmability at the nanoscale and self-assembles via Watson-Crick pairing. These properties make it an ideal candidate for large-scale supramolecular templates. Since the...

Fan Yu, Bochen Li, Sisi Jia et al. · 0 citations
Open access Sep 2026

Chemical Editing Reveals Atomic-Level Control of Supramolecular Structure in Self-Assembling Peptides

Can replacement of single atoms within amino acid sequences redirect peptide self-assembly into different supramolecular structures? To address this question, we investigated a compositionally similar class of bola-amphiphilic peptides that were designed to self-assemble into filamentous nanostructures. The chemical di...

Abhinaba Das, Ayisha Zia, G. N. Eastep et al. · 0 citations
Sep 2026

Hydrogen-Bond Encoding in a Structurally Minimal Cyclochiral Monomer Enables Assembly of Large Cavities Displaying Supramolecular Isomerism.

Large, well-defined molecular cavities are typically constructed from rigid covalent scaffolds, which can limit structural adaptability and increase synthetic complexity. Here, we introduce a hydrogen-bond encoded supramolecular strategy that enables structurally minimal, flexible monomers to assemble into discrete ful...

Qi-Xun Shi, Liang-Shun Guo, Nojus Radzevičius et al. · 0 citations
Open access Aug 2026

A protein–foldamer supramolecular synthon for self-assembled hybrid architectures

Constructing artificial assemblies that combine proteins and synthetic ligands has been hampered by the lack of protein–ligand interfaces that are sufficiently large and organized to enable precise structural control. Here ribosome display selection is used to identify a protein that binds a helical aromatic foldamer b...

Johannes Sigl, Vasily Morozov, Ling-Fei Wang et al. · 1 citation

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