Lanthanide contraction induced coordination-mode transition of phosphotungstate-based complexes for visible-light-driven photocatalytic degradation of ciprofloxacin
Polyoxometalate (POM) based coordination assemblies offer tunable platforms for modulating structural connectivity and photoinduced charge transfer, yet controlled switching of POM between coordinating linkers and non-coordinating counter-anions within a single system remains challenging. Herein, 14 POM-based lanth...