Crystal engineering of a solvent-free isostructural lanthanide series with high Eu(III) and Tb(III) photoluminescence quantum yields
Jian-Jie Xu
Wei Li
Hong-Li Jia
Hong-Liang Han
Xin-Yuan Xie
J. Zuo
Yun Tang
Liao-Yuan Yao
Jian-Ming Liu
Xiang-Fu Meng
Qiong-Hua Jin
Abstract
Constructing isostructural lanthanide molecular crystals provides a useful strategy for correlating coordination geometry, supramolecular packing, and solid-state photophysical behavior. Herein, a family of solvent-free ten-coordinate lanthanide molecular crystals, [Ln(NO3)3(Terpy)(TPPO)] (Ln...