Crystal engineering of a solvent-free isostructural lanthanide series with high Eu(III) and Tb(III) photoluminescence quantum yields
Constructing isostructural lanthanide molecular crystals provides a useful strategy for correlating coordination geometry, supramolecular packing, and solid-state photophysical behavior. Herein, a family of solvent-free ten-coordinate lanthanide molecular crystals, [Ln(NO3)3(Terpy)(TPPO)] (Ln...