Sep 2026· Acta Crystallographica Section C Structural Chemistry· Vol 82, pp. 619 - 626· 0 citations· 8 references
Medicine
Abstract
The solvent-free structure of the thallium(I) salt of the weakly coordinating anion tetrakis[3,5-bis(trifluoromethyl)phenyl]borate, Tl[BC32H12F24], exhibits short Tl⋯F contacts and a supramolecular architecture governed by C—H⋯F hydrogen bonds and weak F⋯F and C—F⋯π interactions. Disorder and tilting of the arene rings generate different close-contact motifs, giving rise to hinge-like intermolecular interactions and pronounced anisotropic thermal expansion along the crystallographic a and b axes.
The synthesis and structure of a homoleptic silver(I) complex with four perfluorobenzonitrile ligands bound in a distorted tetrahedral arrangement combined with perfluoroaluminate counter-ion are described.
Eric Wu, J. D. Watson, Ruo-Ming Tian et al.· Acta Crystallographica Secti...· 0 citations
Bis(tetraethylammonium) dodecacyanododecaborate(2−) crystallizes in the trigonal space group P3. The B12(CN)122– subunit has nearly icosahedral symmetry and interacts with the Et4N+ cation in the structure by multiple weak Csp3–H⋯N hydrogen bonds between CN groups on the anion and methyl or methylene H atoms on the cat...
M. Juhasz, Ashlyn A. Kamin· Acta Crystallographica Secti...· 0 citations
In the title compound, the dihedral angle between the aromatic rings is 77.78 (8)°. In the crystal, the molecules are linked into zigzag ribbons propagating along the [210] direction by pairwise O—H⋯O hydrogen bonds through their two carboxylic acid groups to generate centrosymmetric R22(8) dimers in each case. In addi...
A. Gurbanov, M. Akkurt, Anirban Karmakar et al.· Acta Crystallographica Secti...· 0 citations
Constructing isostructural lanthanide molecular crystals provides a useful strategy for correlating coordination geometry, supramolecular packing, and solid-state photophysical behavior. Herein, a family of solvent-free ten-coordinate lanthanide molecular crystals, [Ln(NO3)3(Terpy)(TPPO)] (Ln...
In the crystal structure of the title compound, the cobalt cations are octahedrally coordinated by two N- and two S-bonding thiocyanate anions and two pyridine-4-carbonitrile ligands and are linked by pairs of μ-1,3-bridging anionic ligands into infinite linear chains. No directional intermolecular interactions are obs...
C. Näther· Acta Crystallographica Secti...· 0 citations
A tridentate N, N, O-donor Schiff base produced a binuclear Cu(II)-complex, [Cu2(L)2(bdc)(H2O)2] (1), (HL = (E)-2-(((2-(dimethylamino)ethyl)imino)methyl)-6-methoxyphenol; bdc2- = 1,4-benzenedicarboxylate) and has structurally been confirmed with monoclinic crystal system and P21/c...
Chittaranjan Sinha, H. Chatterjee, Koushik Saha et al.· New Journal of Chemistry· 0 citations
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