Aug 2026· Dynamics· Vol 6, pp. 30· 1 citation· 20 references
Abstract
We investigate the information-geometric structure of a self-consistent second-virial approximation with the van der Waals form of the second virial coefficient, using the Fisher information as a generating potential. By constructing the associated Hessian metric and scalar curvature, we obtain a geometric description of thermodynamic fluctuations that complements the standard equation-of-state approach. We show that interaction effects enter the Fisher information selectively through their temperature dependence, with attractive interactions playing the dominant role while excluded-volume contributions remain subleading. The Hessian determinant of the Fisher information changes sign along well-defined crossover loci in the reduced parameter space, separating regions of saddle-like and locally convex curvature of the fluctuation landscape, and diverges as D˜−12 at the closure boundary. The scalar curvature diverges at the closure boundary as a simple pole, with a leading term that is universal and independent of the interaction parameters. We derive its exact closed-form expression, which shows that the curvature is negative for weak-to-moderate effective coupling but turns positive in the strong-coupling regime, where the underlying Fisher–Rao metric loses positive-definiteness. The curvature diverges on approach to this metric boundary, which lies strictly inside the mechanically stable region, short of the closure boundary itself. These results demonstrate that Fisher geometry provides a selective probe of interaction-induced fluctuations, capturing how thermal states reorganize under temperature variations rather than encoding phase transitions directly. This approach offers a complementary perspective on interacting systems and suggests new avenues for extending information-geometric methods to more strongly correlated and quantum regimes.
The local form of the virial theorem provides a stringent condition for assessing whether a spatial region behaves as a mechanically closed subsystem in molecular space. While basins derived from the topology of the electron density satisfy this condition by construction, we show that ELF basins do not. The transform...
Cristian J. Guerra, Leandro Ayarde-Henríquez, José L. Burgos et al.· Journal of Physical Chemistr...· 0 citations
We introduce a unified statistical framework for quantifying system-environment coupling by treating the interaction energy VSE as a stochastic variable. Using our proposed reference-particle decomposition, we derive exact, closed-form expressions for the mean and variance of VSE in terms of the single-particle density...
Mohammad Rahbar, C. J. Stein· Journal of Chemical Physics· 0 citations
We investigate the long-time behavior of small solutions to the one-dimensional Hartree equation with the soft Coulomb interaction. The Hartree equation arises as an effective mean-field model for the evolution of many-body quantum systems, while the soft Coulomb potential provides a regularized one-dimensional approxi...
Relativistic effective field theory predicts a topological energy response to a gravitational field that appears at third order in spatial gradients. Here, we investigate how this response emerges in the nonrelativistic Haldane model using a microscopic lattice formulation of curvature-induced deformations. We find tha...
We study the equilibrium structure and long-time behavior of a nonlinear Fokker--Planck equation with diffusion and nonlocal interactions generated by squared simplex volumes. For $1\leq n<d$, the stationary states are isotropic Gaussian measures, and every solution converges to the equilibrium determined by its conser...
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